smtp-user-enum is a tool for enumerating OS-level user accounts on Solaris via the SMTP service (sendmail). Enumeration is performed by inspecting the responses to VRFY, EXPN and RCPT TO commands. It could be adapted to work against other vulnerable SMTP daemons, but this hasn’t been done as of v1.0.
Download Link:- https://github.com/pentestmonkey/smtp-user-enum